Heated crude oil vaporises and enters a fractionating column. Crude-oil hydrocarbons are non-polar, so their main intermolecular
forces are London dispersion forces. Shorter chains have weaker dispersion forces and lower boiling points, so they rise higher;
longer chains have stronger dispersion forces and condense lower down.
Crude oil fractions
What is happening?
Crude oil is heated. Many hydrocarbons vaporise and rise into the fractionating column.
Selected fraction
Showing all fractions.
Hydrocarbons are non-polar. Longer chains have more electrons and a larger contact surface, producing stronger London dispersion forces, higher boiling points and condensation lower in the column.
| Fraction |
Carbon chain |
Approx. temp |
Uses |
Model limitations: this is a conceptual model. Fraction ranges and temperatures vary between sources. The model emphasises chain length and London dispersion forces; molecular shape, branching and hydrocarbon type can also affect boiling point.