Fractional distillation of crude oil

Heated crude oil vaporises and enters a fractionating column. Crude-oil hydrocarbons are non-polar, so their main intermolecular forces are London dispersion forces. Shorter chains have weaker dispersion forces and lower boiling points, so they rise higher; longer chains have stronger dispersion forces and condense lower down.

Animation speed Number of displayed molecules Highlight fraction
Crude oil fractions
What is happening?
Crude oil is heated. Many hydrocarbons vaporise and rise into the fractionating column.
Selected fraction
Showing all fractions.

Hydrocarbons are non-polar. Longer chains have more electrons and a larger contact surface, producing stronger London dispersion forces, higher boiling points and condensation lower in the column.

Fraction Carbon chain Approx. temp Uses

Model limitations: this is a conceptual model. Fraction ranges and temperatures vary between sources. The model emphasises chain length and London dispersion forces; molecular shape, branching and hydrocarbon type can also affect boiling point.

About this simulation

Explore how a temperature gradient in a fractionating column separates crude oil into fractions with different boiling ranges. Students can connect hydrocarbon size, intermolecular forces and boiling point to where fractions condense. Use the model to compare simple and fractional distillation and to discuss why repeated vaporisation and condensation improves separation.

Key concepts: Fractional distillation, Crude oil, Boiling point, Hydrocarbons.